All of my Game Pass time has been spent on XB1, but I have downloaded the client and maybe a game or two from the PC version.
Looking at a list of PC Game Pass games, I highly recommend the following games:
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The Gardens Between
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The Talos Principle
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Battle Chef Brigade
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Forza Horizon 4
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Halo: Master Chief Collection (might not be a complete PC version right now?)
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Minit
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Ori and the Blind Forest (you already said you downloaded this though)
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Orwell: Keeping An Eye On You
Gardens, Talos, and Minit are super high recommends
KCF can't actually be a real person but he is - greengravy
If you smell what the rock is cooking he's cooking crap - ertyu